Astm a380 practice for cleaning, descaling and passivating of stainless steel parts, equipment and systems. However, proprietary passivation processes exist for martensitic stainless steel, which is difficult to passivate, as microscopic discontinuities can form in the surface of a machined part during passivation in a typical nitric acid bath. Stainless steel must be cleaned prior to any passivation procedure. Passivation will not be effective on mild steel because it dissolves it. Traditional passivation the two most common chemicals traditionally used for stainless steel passivation for breweries are citric acid and nitric acid. Conclusions state the effectiveness of citric acid to passivate stainless steel, and the potential to have citric acid replace nitric acid passivation solutions that are. Environmentally friendly citric acid passivation process. Passivation of aerospace stainless steel parts with citric. Citrisurf citric acid passivation stellar solutions. Sep 27, 2019 citric acid passivation of stainless steel used in aerospace applications. Most frequently, the function of passivation is to remove free iron, oxides and other surface contamination. Passivation of corrosion resistant steels features method 1, passivation in nitric acid, and method 2, citric acid, and 8 types. Citrisurf citric acid passivation stainless steel passivation. This specification covers several different types of chemical passivation treatments for stainless steel parts.
It is this chromic oxide layer that is inert passive to the surrounding environment and gives stainless steel its corrosion resistant properties. You can repassivate with citric and ascorbic acid in hot water like we do for ss repassivation after welding or grinding and breaking the surface passivation. Prior to an entering the acid the parts are cleaned to remove any oil and organics. Passivation is a common treatment to maximize the corrosion resistance of stainless steel. Standard specification for chemical passivation treatments. In addition, apt can meet the requirements of any companyspecific nitric or citric acid stainless steel passivation methods. Since chromium is so corrosion resistant, this layer provides greater protection to the already resistant base metal. Passivation acid, a blend of nitric acid and phosphoric acid, at equivalent percent nitric acid concentrations was the most effective at dissolving mild steel. Stainless steel is comprised of a mixture of metals, primarily iron, chromium, nickel and in some cases molybdenum and manganese along.
Passivating stainless steel with nitric or citric acid. Stainless steel is used in many aerospace applications because it is able to maintain its structural integrity over a wide temperature range while remaining chemically inert passive, resisting corrosion and hightemperature oxidation. Passivation of stainless steel astm a967, qqp35, ams 2700. Qqp35c canceled qqp35c, the longtime military specification for stainless steel passivation, has been canceled in favor of astm a967 and ams 2700.
About products or processes from stellar solutions citric acid passivation, phone 847 8542800, fax 847 8542830. This leaves a thin, passive layer usually comprised of chromium and its oxides. Aisi 304 stainless steel samples were submitted to the passivation in both citric and nitric acid baths, in order to compare these two procedures in terms of effectiveness potentiality of the citric acid based passivation and processing time. Many people ask about the differences between nitric acid and citric acid when passivating parts made of stainless steel ss, titanium ti, and other alloys. There are two generally accepted processes for passivation of stainless steel. This paper highlights testing of the citric acid passivation process on stainless steel alloys that are frequently used in the field by the stakeholders dod and nasa. Citric acid passivation of stainless steel used in aerospace applications. Pdf analysis of the acid passivation of stainless steel. Ramco equipment citric acid passivation ramco parts washers. For more information on this and other passivation systems call our factory. The objective should always be to provide low cost parts that are the best. However, citric acid can be purchased in raw form and made into a 10% citric acidwater solution, then heated to 150 degrees for roughly 30 mins to complete the passivation process. Stainless steel passivation works by removing any free iron exposed iron on the surface of the part.
Variations of the citric acid passivation formula variations on the citric acid passivation bath are sometimes called for. Passivation is the treatment of the stainless steel with an oxidizing chemical typically nitric or citric acid which promotes a thin oxidizing layer to form on the surface of the metal. Enlighten me on the use of citric acid in the passivation of our steel products. For example, in the steel mill, the stainless steel may be pickled in an acid. Traditionally the american standards have been used. Passivation is a chemical treatment applied to stainless steel parts to provide resistance to oxidation, rusting and mild chemical attack. The samples were also submitted to the passivation in extracted citric acid bath. To passivate stainless steel parts, they must be submerged in a chemical solution of citric acid or nitric acid for a certain period of time and at a certain temperature. The austenitic grades of stainless steel work well in a citric acid bath with a ph of around 2, but martensitic and precipitation hardening grades are better served by a ph of 3 or higher. Immediately after the removal from the passivating solution, the parts. Citric acid to water amounts for passivation homebrewtalk. The sixth edition, revision f, is used to remove rust from stainless steel.
Citric acid passivation kepco onsite citric acid cleaning and passivation process is based on new technology using safe and environmentally friendly citric acid to remove the free iron from the surface of stainless steel and chromium enrich the surface. The standard of acceptance is whether the product passes the test, not whether the process meets a standard. Even the process aspect of citric acid passivation is easier. Electropolish passivation is a process that uses an acid nitric or citric acid solution to remove the surface iron and other contaminants that cause corrosion in the stainless steel. It seems that nitric acid passivation is better than citric acid passivation. The reference for passivation of stainless steel is. Passivation of 304 and 316 stainless steels in various acid solutions was studied as a function of exposure time and acid concentration. The citrisurf citric acid cleaning and passivation process is based on cutting edge technology using safe and environmentally friendly citric acid to remove the free iron from the surface of stainless steel. It is an acid that can effectively remove iron and its compounds from surfaces. Conclusions state the effectiveness of citric acid to passivate stainless steel, and the potential to have citric acid replace nitric acid passivation solutions that are currently being used in the aerospace industry. Citric acid passivation uses concentrated citric acid to passivate metals like stainless steel and titanium. Citric acid passivation of stainless steel pdf conclusions on page 49, tldr. Passivation is the controlled oxidation of the nickel on the surface of stainless steel.
Nitric acid, citric acid, and the commercial citrisurf a. We did an eds and xps test on samples for both types of passivation. Specification astm a 967 standard specification for chemical passivationtreatments for stainless steel parts and ams 2700 passivation treatments for corrosionresistant steel, both allow for the use of citric acid in place of nitric acid. The passivation process removes exogenous iron, createsrestores a passive oxide layer that prevents. In the past, manufacturers avoided citric acid due to potential organic growth and molding issues. Jul 30, 2015 citric acid passivation of stainless steel pdf conclusions on page 49, tldr. Sae standard for passivation of corrosion resistant steels.
The study supports the effectiveness of citric acid to passivate stainless steel, and the potential to have citric acid replace nitric acid passivation solutions that are currently being used in the aerospace industry. Pickling is the process used to remove weld heat tinted layers from the surface of stainless steel fabrications, where the steels surface chromium level has been reduced. This thin layer will help protect the metal from chemical attack. Many applications particularly in the medical and semiconductor industries require that stainless steel instruments and other components be completely corrosion resistant or passivated. The passivation process removes free iron ferric material from the surface of the parts that can be created during finishing operations such as. Using citric acid to protect stainless steel parts from corrosion. Lastly, several commercial products have even been introduced to fulfill the needs of passivation for food safe 304316 stainless, such as citrisurf. All surfaces contaminated with oil, grease, chips, grinding dust, lapping compound, buffing compound, coolant, andor swarf must be removed. This removes foreign matter like free iron from the surface, but does not remove the heat tint or oxide scale that may be left behind by welding or heat treating. Citric acid passivation is the use of citric acid to passivate stainless steel ss and other alloys to prevent corrosion. Citric acid passivation solution for stainless steel. Citric acid provides passivation of stainless steel while providing worker and environmental safety, versatility, ease of use, less maintenance and lower costs. This article tells you everything you need to know. Citric acid is also sometimes used for passivating stainless steel.
The passivation process removes free iron ferric material from the surface of the parts that can be created during finishing operations such as milling, buffing, lapping, cutting, etc. Im having a hard time understanding when passivation of stainless is warranted, and im eager for your thoughts there. However, citric acid can be purchased in raw form and made into a 10% citric acid water solution, then heated to 150 degrees for roughly 30 mins to complete the passivation process. Will troske, advanced plating technologies stainless steel is an inherently corrosion resistant material, however when stainless steel is machined, formed or fabricated free iron can be introduced to the surface that can corrode independent of the base material. Advanced plating technologies, offers passivation of stainless steel to all methods listed within astm a967, ams 2700 and qqp35. Passivation is the process of forming a passive layer of chromium oxide on the surface of stainless steel to protect it from corrosion. Mixtures of nitric and hydrofluoric acids are usually used for pickling stainless steels. Citric acid is an intriguing alternative to nitric acid. Today, citric acid has improved leaps and bounds with new formulations for biocides. The concentrated citric acid works to pull iron from the surface, then forms a protective layer on the outside of the part like a protective shell.
We have been using both nitric acid with sodium dichromate and citric acid for our passivation process for 440c. Citric acid passivation of stainless steel products finishing. This is done by adding a chemical that removes free iron and allows chromium oxide to form. By removing free iron ions and forming a protective passive oxide layer on the surface, the stainless steel or other metal becomes highly resistant to rust. Passivating stainless steel for superior corrosion resistance. Nitric acid is generally used and involves several ecological problems, citric acid could be a promising.
Nitric acid and sometimes with dichromate depending on the alloy also removes the free iron but then control oxidizes the surface to prevent further oxidation unless exposed to a reducing liquid or chloride. Stainless steel citric acid passivation austral wright. The chromium, in the presence of air, especially oxygen, forms a thin, hard adherent film of chromium oxide on the surface of the alloy. The samples were also submitted to the passivation in. Developments in citric acid passivation of stainless steel. The new specifications allow you to do your stainless steel passivation with state of the art citrisurf citric acid passivation technology that is safe and environmentally friendly. Both are effective in establishing the protective chromium oxide surface of the stainless steel, but differ in their.
Developments in citric acid passivation of stainless steel r. Mchenry, il usa stainless steel passivation is a mysterious process to many, but one that is important in the metal finishing industry to get the full benefit from corrosion resistant steel alloys. This removes foreign matter like free iron from the surface, but does not remove the heat tint or oxide. Specifications for passivation treatments for stainless steels. Mark kolody escnasa corrosion technology laboratory. Solution strengths of 410% citric acid are specified for passivation treatments in astm a967. A 5050 mix of 1 lb acid blend in 4gallons of water, heated to 180 degrees, and left to cool for about 68 hours will extract the soluble iron and rebuild the oxides to protect the. Citric acid passivation the best method for cleaning and passivating stainless steel. Passivation of aerospace stainless parts with citric acid. Algonquin, illinois passivation of stainless steel.